{"created":"2023-05-15T12:30:57.198357+00:00","id":521,"links":{},"metadata":{"_buckets":{"deposit":"aacd21be-262b-4c0a-ad72-c071a923f009"},"_deposit":{"created_by":2,"id":"521","owners":[2],"pid":{"revision_id":0,"type":"depid","value":"521"},"status":"published"},"_oai":{"id":"oai:fit.repo.nii.ac.jp:00000521","sets":["256:257:261"]},"author_link":["2563","2567","2565","2564","2562","2566"],"item_3_alternative_title_23":{"attribute_name":"タイトル（ヨミ）","attribute_value_mlt":[{"subitem_alternative_title":"フッソ ヨンケイソ ウンモ ナノシート エキショウ ト ポリ － Ｎ － イソプロピルアクリルアミド ノ フクゴウカ ニヨル イホウセイ ヒドロゲル ノ ゴウセイ"}]},"item_3_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2011-02","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"2","bibliographicPageEnd":"122","bibliographicPageStart":"117","bibliographicVolumeNumber":"43","bibliographic_titles":[{"bibliographic_title":"福岡工業大学研究論集"}]}]},"item_3_description_17":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_3_description_47":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"論文(Article)","subitem_description_type":"Other"}]},"item_3_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"Anisotropic hydrogels were synthesized by radical polymerization of N-isopropylacrylamide in the liquid crystalline aqueous colloids of fluortetrasilicic mica (FTSM) nanosheets. As the concentration of FTSM and/or chemical crosslinker (N,N’-methylenebisacrylamide) increased, the swelling degree at equilibrium decreased, while the gels became more elastic but more brittle. The gels synthesized in a thin glass capillary showed unilateral orientation of the optical axis over whole the gel domain (several cm)due to concentrically aligned nanosheets in the cylindrical gel. Birefringence index △n increased as the nanosheet concentration increased. The diameter of the capillary and the lateral size of the nanosheets also affected △n. Due to the anisotropy in the structure of the hybrid gels,the gels also showed anisotropy in thermally-induced volume phase transition at around 34℃ upon increasing the temperature. The degree of shrinkage as well as its anisotropy basically decreased as the content of FTSM increased.","subitem_description_type":"Other"}]},"item_3_full_name_2":{"attribute_name":"著者(ヨミ)","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"2564","nameIdentifierScheme":"WEKO"}],"names":[{"name":"カマチ, ユウイチロウ"}]},{"nameIdentifiers":[{"nameIdentifier":"2565","nameIdentifierScheme":"WEKO"}],"names":[{"name":"ミヤモト, ノブヨシ"}]}]},"item_3_full_name_3":{"attribute_name":"別言語の著者","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"2566","nameIdentifierScheme":"WEKO"}],"names":[{"name":"KAMACHI, Yuichiro"}]},{"nameIdentifiers":[{"nameIdentifier":"2567","nameIdentifierScheme":"WEKO"}],"names":[{"name":"MIYAMOTO, Nobuyoshi"}]}]},"item_3_publisher_37":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"福岡工業大学"}]},"item_3_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"02876620","subitem_source_identifier_type":"ISSN"}]},"item_3_text_18":{"attribute_name":"形態","attribute_value_mlt":[{"subitem_text_value":"1845467 bytes"}]},"item_3_text_38":{"attribute_name":"出版者（ヨミ）","attribute_value_mlt":[{"subitem_text_value":"フクオカ コウギョウ ダイガク"}]},"item_3_text_39":{"attribute_name":"別言語の出版者","attribute_value_mlt":[{"subitem_text_value":"Fukuoka Institute of Technology"}]},"item_3_text_48":{"attribute_name":"資源タイプ・ローカル","attribute_value_mlt":[{"subitem_text_value":"紀要論文"}]},"item_3_text_49":{"attribute_name":"資源タイプ・NII","attribute_value_mlt":[{"subitem_text_value":"Departmental Bulletin Paper"}]},"item_3_text_50":{"attribute_name":"資源タイプ・DCMI","attribute_value_mlt":[{"subitem_text_value":"text"}]},"item_3_text_51":{"attribute_name":"資源タイプ・ローカル表示コード","attribute_value_mlt":[{"subitem_text_value":"01"}]},"item_3_version_type_19":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"蒲池, 雄一郎"}],"nameIdentifiers":[{"nameIdentifier":"2562","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"宮元, 展義"}],"nameIdentifiers":[{"nameIdentifier":"2563","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-09-14"}],"displaytype":"detail","filename":"11478-1325_p117.pdf","filesize":[{"value":"1.8 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"11478-1325_p117.pdf","url":"https://fit.repo.nii.ac.jp/record/521/files/11478-1325_p117.pdf"},"version_id":"a2c56007-a273-471b-9e1b-9645489fd86b"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"nanosheet","subitem_subject_scheme":"Other"},{"subitem_subject":"liquid crystal","subitem_subject_scheme":"Other"},{"subitem_subject":"hydrogel","subitem_subject_scheme":"Other"},{"subitem_subject":"anisotropy","subitem_subject_scheme":"Other"},{"subitem_subject":"nanosheet","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"liquid crystal","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"hydrogel","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"anisotropy","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"フッ素四ケイ素雲母ナノシート液晶とポリ-N-イソプロピルアクリルアミドの複合化による異方性ヒドロゲルの合成","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"フッ素四ケイ素雲母ナノシート液晶とポリ-N-イソプロピルアクリルアミドの複合化による異方性ヒドロゲルの合成"},{"subitem_title":"Synthesis of anisotropic hydrogels of poly(N -isopropylacrylamide) hybridized with nanosheet liquid crystal of fluortetrasilicic mica","subitem_title_language":"en"}]},"item_type_id":"3","owner":"2","path":["261"],"pubdate":{"attribute_name":"公開日","attribute_value":"2019-09-12"},"publish_date":"2019-09-12","publish_status":"0","recid":"521","relation_version_is_last":true,"title":["フッ素四ケイ素雲母ナノシート液晶とポリ-N-イソプロピルアクリルアミドの複合化による異方性ヒドロゲルの合成"],"weko_creator_id":"2","weko_shared_id":2},"updated":"2023-05-15T13:55:15.188106+00:00"}