{"created":"2023-05-15T12:30:45.580101+00:00","id":329,"links":{},"metadata":{"_buckets":{"deposit":"cad648cb-371b-421c-a00f-73f87f6ab2d4"},"_deposit":{"created_by":2,"id":"329","owners":[2],"pid":{"revision_id":0,"type":"depid","value":"329"},"status":"published"},"_oai":{"id":"oai:fit.repo.nii.ac.jp:00000329","sets":["256:257:268"]},"author_link":["1489","1482","1484","1483","1485","1491","1486","1481","1488","1480","1490","1487"],"item_3_alternative_title_23":{"attribute_name":"タイトル（ヨミ）","attribute_value_mlt":[{"subitem_alternative_title":"サンカ カンゲン シキソ デンカイ ジュウゴウマク ノ デンキ カガク トクセイ ト チロシナーゼ オ モチイタ ２，４ジクロロフェノール センサ エ ノ オウヨウ"}]},"item_3_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2007-02","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"2","bibliographicPageEnd":"184","bibliographicPageStart":"177","bibliographicVolumeNumber":"39","bibliographic_titles":[{"bibliographic_title":"福岡工業大学研究論集"}]}]},"item_3_description_17":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_3_description_47":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"論文(Article)","subitem_description_type":"Other"}]},"item_3_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"Three redox dyes, Neutral Red (NR), Brilliant Cresyl Blue (BCB), and Toluidine Blue (TB), which have similar substituents on phenazine, phenoxazine, and phenothiazine ring structures independently, have been electropolymerized with cyclic voltmmometric technique onto graphite electrodes. These polyazines were found to show inherent redox activities, while the redox potentials were shifted to the positive potential region compared with those of the corresponding monomer. Enzyme electrodes constructed with tyrosinase (EC 1.14.18.1) showed the sensor response against 2, 4-dichlorophenol (2, 4-DCP) employed as a model substrate, and it was observed that the response current could be increased by introducing a layer of poly (NR) or poly (BCB) on the surface of graphite electrodes. It is suggested that these redox active polyazine layers act as electron mediators, though unambiguous evidence has not been obtained by examining the change of cyclic voltammograms with addition of the substrate.","subitem_description_type":"Other"}]},"item_3_full_name_2":{"attribute_name":"著者(ヨミ)","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"1484","nameIdentifierScheme":"WEKO"}],"names":[{"name":"カワカミ, ミツヤス"}]},{"nameIdentifiers":[{"nameIdentifier":"1485","nameIdentifierScheme":"WEKO"}],"names":[{"name":"オオハラ, ユウタ"}]},{"nameIdentifiers":[{"nameIdentifier":"1486","nameIdentifierScheme":"WEKO"}],"names":[{"name":"コウヤ, ヒデカズ"}]},{"nameIdentifiers":[{"nameIdentifier":"1487","nameIdentifierScheme":"WEKO"}],"names":[{"name":"アマダ, ケイ"}]}]},"item_3_full_name_3":{"attribute_name":"別言語の著者","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"1488","nameIdentifierScheme":"WEKO"}],"names":[{"name":"KAWAKAMI, 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ダイガク"}]},"item_3_text_39":{"attribute_name":"別言語の出版者","attribute_value_mlt":[{"subitem_text_value":"Fukuoka Institute of Technology"}]},"item_3_text_48":{"attribute_name":"資源タイプ・ローカル","attribute_value_mlt":[{"subitem_text_value":"紀要論文"}]},"item_3_text_49":{"attribute_name":"資源タイプ・NII","attribute_value_mlt":[{"subitem_text_value":"Departmental Bulletin Paper"}]},"item_3_text_50":{"attribute_name":"資源タイプ・DCMI","attribute_value_mlt":[{"subitem_text_value":"text"}]},"item_3_text_51":{"attribute_name":"資源タイプ・ローカル表示コード","attribute_value_mlt":[{"subitem_text_value":"02"}]},"item_3_text_79":{"attribute_name":"コメント","attribute_value_mlt":[{"subitem_text_value":"著者所属　：　生命環境科学科（Department of Life, Environment and Materials Science）"}]},"item_3_version_type_19":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"川上, 満泰"}],"nameIdentifiers":[{"nameIdentifier":"1480","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"大原, 友太"}],"nameIdentifiers":[{"nameIdentifier":"1481","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"神谷, 英和"}],"nameIdentifiers":[{"nameIdentifier":"1482","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"天田, 啓"}],"nameIdentifiers":[{"nameIdentifier":"1483","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-09-14"}],"displaytype":"detail","filename":"11478-445_p177.pdf","filesize":[{"value":"481.4 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"11478-445_p177.pdf","url":"https://fit.repo.nii.ac.jp/record/329/files/11478-445_p177.pdf"},"version_id":"d1bfcd38-88fb-4791-a46b-59bdbc2ec20f"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"redox dyes","subitem_subject_scheme":"Other"},{"subitem_subject":"electropolymerization","subitem_subject_scheme":"Other"},{"subitem_subject":"tyrosinase","subitem_subject_scheme":"Other"},{"subitem_subject":"2, 4-dichlorophenol","subitem_subject_scheme":"Other"},{"subitem_subject":"biosensor","subitem_subject_scheme":"Other"},{"subitem_subject":"redox dyes","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"electropolymerization","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"tyrosinase","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"2, 4-dichlorophenol","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"biosensor","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin 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